Glossary entry

Chinese term or phrase:

伯正碳离子

English translation:

primary carbocation

Added to glossary by Huijun Suo
Feb 3, 2008 06:45
16 yrs ago
Chinese term

伯正碳离子

Chinese to English Science Chemistry; Chem Sci/Eng
“异丁烯与H+结合转化为伯正碳离子,伯正碳离子不稳定二发生重排反应,形成叔正碳离子“

”伯正碳,叔正碳离子“对应的英文是什么?谢谢!
Proposed translations (English)
4 +2 primary carbocation
Change log

Feb 4, 2008 06:03: Huijun Suo changed "Edited KOG entry" from "<a href="/profile/619548">Peggy Huang's</a> old entry - "伯正碳离子"" to ""primary carbocation""

Proposed translations

+2
47 mins
Selected

primary carbocation

伯正碳离子 primary carbocation (1ºR+)
仲正碳离子 secondary carbocation (2ºR+)
叔正碳离子 tertiary carbocation (3ºR+)

http://www.chemguide.co.uk/mechanisms/eladd/carbonium.html
CARBOCATIONS (or CARBONIUM IONS)

All carbocations (previously known as carbonium ions) carry a positive charge on a carbon atom. The name tells you that - a cation is a positive ion, and the "carbo" bit refers to a carbon atom. However there are important differences in the structures of various types of carbocations.

Primary carbocations

In a primary (1°) carbocation, the carbon which carries the positive charge is only attached to one other alkyl group.

http://www.britannica.com/eb/article-9020266/carbonium-ion
carbonium ion

any member of a class of organic molecules with positive charges localized at a carbon atom. Certain carbonium ions can be prepared in such a way that they are stable enough for study; more frequently they are only short-lived forms (intermediates) occurring during chemical reactions.

http://www.hoodong.com/wiki/正碳离子
正碳离子
carbonium ion
带有正电荷的含碳离子。一类重要的活性中间体。可用
R3C+表示(R为烷基)。

http://auntyellow.yculblog.com/post.200263.html
1901年至2000年诺贝尔化学奖获得者(四)
1994年
(美)G.奥拉(George Andrew Olah, 1927- )(出生于匈牙利),在超强酸的作用下首次得到正碳离子,过去化学家只是用正碳离子来解释一些有机反应的机理,而正碳离子的发现为这样的机理提供了直接证据。
Note from asker:
Thank you very much, Huijun!
Peer comment(s):

agree Naikei Wong
3 mins
Thanks!
agree ysun
7 hrs
Thanks!
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4 KudoZ points awarded for this answer.
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